Vanadinite - www.Crystals.eu

Vanadinite

Vanadinite • lead chlorovanadate — Pb₅(VO₄)₃Cl (apatite‑group) Crystal system: Hexagonal • Habit: short hexagonal prisms, often barrel‑shaped, rosettes, crusts Color: cherry‑red → orange‑red → brownish; transparency: translucent to opaque Mohs: ~3–4 • SG: ~6.8–7.2 (surprisingly heavy) • Luster: resinous to sub‑adamantine Classic associations: wulfenite, mimetite, pyromorphite, cerussite, barite

Vanadinite — Cherry‑Red Hexagons from the Desert’s Oxidation Zones

Vanadinite looks like a box of cinnamon candies got spilled across the rock. Those little hexagonal barrels grow in the near‑surface weathering zone of lead deposits, painting pockets and fractures with saturated reds and oranges. Pick one up and you’ll notice the heft right away—lead gives it gravitas, the color does the rest.

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What it is
A secondary lead mineral (chlorovanadate) from the oxidation zone of Pb ore bodies; a member of the apatite‑group along with pyromorphite & mimetite
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Why it captivates
Intense cherry‑to‑orange red, sharp hexagonal crystals, and a resinous glow that holds color even in small sizes
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Care snapshot
Soft & brittle; dust gently, avoid soaking/chemicals; handle specimen dust thoughtfully and store with support

Identity & Naming 🔎

Apatite‑group cousin

Vanadinite is the vanadate analog in the apatite supergroup: compare it with pyromorphite Pb₅(PO₄)₃Cl (phosphate) and mimetite Pb₅(AsO₄)₃Cl (arsenate). All share the same hexagonal scaffold but swap the central anion group, which nudges color and chemistry.

Name & color

Named for vanadium, the element that provides the vivid reds and oranges (as VO₄³⁻ units). Iron impurities and weathering can push tones toward brownish red and honey.

Collector shorthand: “hex barrels on barite” usually means vanadinite; “thin plates” usually means wulfenite. The pairing is common and photogenic.

Where It Forms 🧭

Oxidized lead deposits

As galena and other lead sulfides weather near the surface, oxygen‑rich waters mobilize lead and vanadate components. In fractures and cavities, they precipitate as vanadinite—often alongside wulfenite, mimetite, pyromorphite, cerussite, and iron oxides.

Crystal habits

Expect short hexagonal prisms, sometimes with barrel‑like faces from horizontal striations; also botryoidal crusts and tight micro‑rosettes. Thin edges can glow orange‑red in transmitted light.

Why deserts love it

Dry climates slow dissolution and let delicate crystals survive; that’s why so many famous specimens hail from Morocco, Mexico, and the American Southwest.

Like a sunset in slow motion: sulfides rust, elements travel, and vanadinite crystallizes in neat hexagons that look hand‑placed.

Palette & Pattern Vocabulary 🎨

Palette

  • Cherry red — classic, saturated barrels.
  • Orange‑red — common on thin edges and younger growth.
  • Honey/brown — iron‑tinted or weathered zones.
  • Smoky matrix — limonite/hematite backgrounds.
  • Barite buff — pale host blades that make red pop.

Luster ranges from resinous (glassy syrup) to sub‑adamantine on fresh faces—part of why tiny crystals photograph so well.

Pattern words

  • Barrel clusters — stubby prisms packed like honeycomb.
  • Rosettes — radiating hexagons on barite or limonite plates.
  • Drusy carpets — sparkly microcrystals lining cavities.
  • Chocolate‑chip barite — red dots scattered on pale blades.

Photo tip: Use low, raking light at ~25–35°. Add a small white reflector to fill shadows; reds stay rich, edges show that orange “glow.”


Physical & Optical Details 🧪

Property Typical Range / Note
Chemistry Pb₅(VO₄)₃Cl — lead chlorovanadate; apatite‑group
Crystal system / Habit Hexagonal; short prisms, barrel‑like crystals, rosettes, botryoidal crusts
Color / Luster Cherry‑ to orange‑red, brownish; resinous to sub‑adamantine luster
Hardness (Mohs) ~3–4 (soft; handle accordingly)
Specific gravity ~6.8–7.2 (heavy for its size)
Streak Yellowish‑white
Cleavage / Fracture Cleavage poor/indistinct; fracture uneven to conchoidal; brittle
Optics Uniaxial; very high refractive indices (>2), strong birefringence; often shows internal reflections on tilt
Fluorescence Usually inert
Associations Wulfenite, mimetite, pyromorphite, cerussite, anglesite, barite, limonite
Treatments Generally untreated; specimen mounts may use adhesives for stability
Plain‑English optics: extremely high refractive indices give tiny crystals a bold, glass‑syrup shine—why even thumbnails look punchy.

Under the Loupe 🔬

Hex anatomy

Faces are often horizontally striated, giving a ribbed, barrel‑like look. Cross‑sections show clean hexagons; edges may transmit orange light.

Color zoning

Some crystals show core‑rim zoning from red to orange; a tilt test under a penlight reveals brighter edges and slightly darker cores.

Host clues

On barite, crystals sit neatly on tabular blades; on limonite/hematite, they sprinkle cavities like candy—context helps distinguish from look‑alikes.


Look‑Alikes & Mix‑ups 🕵️

Wulfenite

Lead molybdate in thin square/rectangular plates (tetragonal), color yellow‑orange to red. Vanadinite forms short hex prisms—different silhouette.

Mimetite & pyromorphite

Same structure, different anions. Mimetite (arsenate) trends yellow‑orange; pyromorphite (phosphate) often green. All can form barrels; chemistry tests or locality context help separate them.

Crocoite

Lead chromate with long, slender prisms (monoclinic) and fiery orange‑red. Vanadinite is stubbier and heavier‑looking on the matrix.

Realgar

As₄S₄, soft (Mohs ~1.5–2), often massive or prismatic but light‑sensitive and far softer; lacks hexagonal barrels.

Rhodochrosite

MnCO₃ can be cherry red but shows good cleavage and often scalenohedral/rhombic habits; SG much lower (~3.5–3.7).

Quick checklist

  • Stubby hexagonal crystals with resinous shine?
  • Cherry‑to‑orange red, heavy for size?
  • Found with barite/wulfenite in oxidized Pb deposits? → Vanadinite.

Localities & Stories 📍

Where it shines

Famous specimens come from Morocco (Mibladen & Taouz districts — iconic cherry‑red barrels), Mexico (Los Lamentos, Chihuahua — deep orange crystals), and the USA (Arizona: Apache, Old Yuma, and other oxidized Pb‑Cu mines; New Mexico). Attractive material also occurs in Namibia, Zambia, and parts of Europe.

What people do with it

Primarily a collector specimen, occasionally cut into small cabochons or beads (more as curiosities; it’s soft). Historically a minor ore of vanadium, but its true calling is “photogenic shelf star.”

Labeling idea: “Vanadinite — Pb chlorovanadate — hexagonal barrels — host (barite/limonite) — locality.” Crisp and complete.

Care & Display Notes 🧼🧯

Everyday care

  • Dust gently with an air bulb or very soft brush; avoid soaking and household cleaners.
  • Keep specimens on a stable cradle; crystals are brittle and heavy clusters can detach from soft matrix.
  • Mind the heft—support bases when moving pieces to prevent sudden shifts.

Handling rough

  • Work dry; avoid grinding/polishing dust on open benches.
  • After handling rough or trimming, wash hands and tidy dust—good workshop hygiene for any lead‑bearing species.
  • Ultrasonics/steam can loosen crystals or undercut matrix—skip them.

Display tips

  • Use a dark, matte plinth to make reds glow.
  • Light low and warm‑neutral; a small reflector keeps faces crisp without bleaching color.
  • Consider clear covers for drusy carpets to keep dust off without killing sparkle.
Curator trick: put a thin white card just out of frame opposite your key light—the micro‑faces catch it and the whole cluster looks brighter.

Hands‑On Demos 🔍

Hex silhouette

Place a single crystal on a light box and view the end‑on outline—it’s a crisp hexagon. Rotating it shows the barrel striations march around the sides.

Heft test

Offer a small vanadinite piece and a similarly sized quartz pebble: visitors are always surprised by the weight difference. Heavy, tiny, memorable.

Vanadinite is the geological equivalent of a red velvet cupcake—small, irresistible, and surprisingly dense.

Questions ❓

Is vanadinite safe to handle?
As a cabinet specimen, yes—just avoid creating or inhaling dust and wash hands after trimming rough. Store away from acids and aggressive cleaners.

Can it be used in jewelry?
It’s soft and brittle; occasional small cabochons exist, but vanadinite is happiest as a display mineral.

Why does it often grow on barite?
Barite is a common gangue mineral in oxidized Pb deposits; its tabular blades make a perfect stage for vanadinite’s hexagons.

Does the color fade?
Not under typical indoor lighting. Keep away from harsh chemicals and prolonged soaking, which can dull luster or affect matrix.

Vanadinite vs. mimetite vs. pyromorphite—quick tip?
Hue helps (red/orange = vanadinite; yellow/orange = mimetite; green/yellow = pyromorphite), but all can overlap. Locality context and simple chemistry tests settle close calls.

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